Synthesis of [(tmeda)LiCH₂PMe₂Li(tmeda)CH₂PMe₂] (tmeda = tetramethyl- ethylenediamine) and of a binuclear zirconocene phosphine functionalized ketene complex, [(η-C₅H₅)₂CIZr(PMe₂CH=CO)ZrCI(η-C₅H₅)₂] (both structurally characterized), the latter via carbonylation of ‘[(η-C₅H₅)₂ZrCI(CH₂PMe₂)]’

Lutz M. Engelhardt, Geraldine E. Jacobsen, Colin L. Raston, Allan H. White

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Chemistry

Medicine and Dentistry

Synthesis of [(tmeda)LiCH2PMe2Li(tmeda)CH2PMe2] (tmeda = tetramethyl- ethylenediamine) and of a binuclear zirconocene phosphine functionalized ketene complex, [(η-C5H5)2CIZr(PMe2CH=CO)ZrCI(η-C5H5)2] (both structurally characterized), the latter via carbonylation of ‘[(η-C5H5)2ZrCI(CH2PMe2)]’

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Chemistry

Medicine and Dentistry