TY - JOUR
T1 - The chemistry of Eremophila SPP-VI*. Stereochemistry and crystal structure of dihydroxyserrulatic acid
AU - Croft, Kevin D.
AU - Ghisalberti, Emilio L.
AU - Jefferies, Philip R.
AU - Raston, Colin L.
AU - White, Allan H.
AU - Hall, Sydney R.
PY - 1977
Y1 - 1977
N2 - The structure of the title compound has been shown to be (6), a diterpenoid analogue of the cadinene group. Standard degradation has given the naphthalene (14). The relative stereochemistry is established by crystal structure of dihydroxyserrulatic acid which has been determined by X-ray diffraction at 295 K, and refined by least squares to a residual of 0.059 for 1480 observed reflections. Crystals are orthorhombic, P 212121, a = 15.514 (3), b=14.029 (3), c=8.681 (2)Å, Z=4.
AB - The structure of the title compound has been shown to be (6), a diterpenoid analogue of the cadinene group. Standard degradation has given the naphthalene (14). The relative stereochemistry is established by crystal structure of dihydroxyserrulatic acid which has been determined by X-ray diffraction at 295 K, and refined by least squares to a residual of 0.059 for 1480 observed reflections. Crystals are orthorhombic, P 212121, a = 15.514 (3), b=14.029 (3), c=8.681 (2)Å, Z=4.
UR - http://www.scopus.com/inward/record.url?scp=20444364619&partnerID=8YFLogxK
U2 - 10.1016/0040-4020(77)88007-1
DO - 10.1016/0040-4020(77)88007-1
M3 - Article
AN - SCOPUS:20444364619
SN - 0040-4020
VL - 33
SP - 1475
EP - 1480
JO - Tetrahedron
JF - Tetrahedron
IS - 12
ER -