The chemistry of Eremophila SPP-VI*. Stereochemistry and crystal structure of dihydroxyserrulatic acid

Kevin D. Croft; Emilio L. Ghisalberti; Philip R. Jefferies; Colin L. Raston; Allan H. White; Sydney R. Hall

doi:10.1016/0040-4020(77)88007-1

The chemistry of Eremophila SPP-VI^*. Stereochemistry and crystal structure of dihydroxyserrulatic acid

Kevin D. Croft
, Emilio L. Ghisalberti
, Philip R. Jefferies
, Colin L. Raston
, Allan H. White
, Sydney R. Hall

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

The structure of the title compound has been shown to be (6), a diterpenoid analogue of the cadinene group. Standard degradation has given the naphthalene (14). The relative stereochemistry is established by crystal structure of dihydroxyserrulatic acid which has been determined by X-ray diffraction at 295 K, and refined by least squares to a residual of 0.059 for 1480 observed reflections. Crystals are orthorhombic, P 2₁2₁2₁, a = 15.514 (3), b=14.029 (3), c=8.681 (2)Å, Z=4.

Original language	English
Pages (from-to)	1475-1480
Number of pages	6
Journal	Tetrahedron
Volume	33
Issue number	12
DOIs	https://doi.org/10.1016/0040-4020(77)88007-1
Publication status	Published - 1977
Externally published	Yes

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title = "The chemistry of Eremophila SPP-VI*. Stereochemistry and crystal structure of dihydroxyserrulatic acid",

abstract = "The structure of the title compound has been shown to be (6), a diterpenoid analogue of the cadinene group. Standard degradation has given the naphthalene (14). The relative stereochemistry is established by crystal structure of dihydroxyserrulatic acid which has been determined by X-ray diffraction at 295 K, and refined by least squares to a residual of 0.059 for 1480 observed reflections. Crystals are orthorhombic, P 212121, a = 15.514 (3), b=14.029 (3), c=8.681 (2){\AA}, Z=4.",

author = "Croft, \{Kevin D.\} and Ghisalberti, \{Emilio L.\} and Jefferies, \{Philip R.\} and Raston, \{Colin L.\} and White, \{Allan H.\} and Hall, \{Sydney R.\}",

year = "1977",

doi = "10.1016/0040-4020(77)88007-1",

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T1 - The chemistry of Eremophila SPP-VI*. Stereochemistry and crystal structure of dihydroxyserrulatic acid

AU - Croft, Kevin D.

AU - Ghisalberti, Emilio L.

AU - Jefferies, Philip R.

AU - Raston, Colin L.

AU - White, Allan H.

AU - Hall, Sydney R.

PY - 1977

Y1 - 1977

N2 - The structure of the title compound has been shown to be (6), a diterpenoid analogue of the cadinene group. Standard degradation has given the naphthalene (14). The relative stereochemistry is established by crystal structure of dihydroxyserrulatic acid which has been determined by X-ray diffraction at 295 K, and refined by least squares to a residual of 0.059 for 1480 observed reflections. Crystals are orthorhombic, P 212121, a = 15.514 (3), b=14.029 (3), c=8.681 (2)Å, Z=4.

AB - The structure of the title compound has been shown to be (6), a diterpenoid analogue of the cadinene group. Standard degradation has given the naphthalene (14). The relative stereochemistry is established by crystal structure of dihydroxyserrulatic acid which has been determined by X-ray diffraction at 295 K, and refined by least squares to a residual of 0.059 for 1480 observed reflections. Crystals are orthorhombic, P 212121, a = 15.514 (3), b=14.029 (3), c=8.681 (2)Å, Z=4.

UR - https://www.scopus.com/pages/publications/20444364619

U2 - 10.1016/0040-4020(77)88007-1

DO - 10.1016/0040-4020(77)88007-1

M3 - Article

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SN - 0040-4020

VL - 33

SP - 1475

EP - 1480

JO - Tetrahedron

JF - Tetrahedron

IS - 12

ER -

The chemistry of Eremophila SPP-VI^*. Stereochemistry and crystal structure of dihydroxyserrulatic acid

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