The Crystal and Molecular Structure of (±)-(‘E, ’)-N-Acetylpiperidine-2-carboxylic Acid

Ian D. Rae; Colin L. Raston; Allan H. White

doi:10.1071/CH9800215

The Crystal and Molecular Structure of (±)-(‘E, ’)-N-Acetylpiperidine-2-carboxylic Acid

Ian D. Rae, Colin L. Raston, Allan H. White

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16 Citations (Scopus)

Abstract

The crystal structure of N-acetylpiperidine-2-carboxylic acid has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0.039 for 846 ‘observed’ reflections. Crystals are orthorhombic, with space group P bca, a 13.684(6), b 11.602(4), c 11.171(4) Å, Z 8. The ring is a chair structure in which, contrary to an earlier proposal based on 1H n.m.r. studies, there is almost perfect staggering about the C(2)-C(3) bond.

Original language	English
Pages (from-to)	215-219
Number of pages	5
Journal	Australian Journal of Chemistry
Volume	33
Issue number	1
DOIs	https://doi.org/10.1071/CH9800215
Publication status	Published - 1980
Externally published	Yes

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title = "The Crystal and Molecular Structure of (±)-({\textquoteleft}E, {\textquoteright})-N-Acetylpiperidine-2-carboxylic Acid",

abstract = "The crystal structure of N-acetylpiperidine-2-carboxylic acid has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0.039 for 846 {\textquoteleft}observed{\textquoteright} reflections. Crystals are orthorhombic, with space group P bca, a 13.684(6), b 11.602(4), c 11.171(4) {\AA}, Z 8. The ring is a chair structure in which, contrary to an earlier proposal based on 1H n.m.r. studies, there is almost perfect staggering about the C(2)-C(3) bond.",

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year = "1980",

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AU - Raston, Colin L.

AU - White, Allan H.

PY - 1980

Y1 - 1980

N2 - The crystal structure of N-acetylpiperidine-2-carboxylic acid has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0.039 for 846 ‘observed’ reflections. Crystals are orthorhombic, with space group P bca, a 13.684(6), b 11.602(4), c 11.171(4) Å, Z 8. The ring is a chair structure in which, contrary to an earlier proposal based on 1H n.m.r. studies, there is almost perfect staggering about the C(2)-C(3) bond.

AB - The crystal structure of N-acetylpiperidine-2-carboxylic acid has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least squares to a residual of 0.039 for 846 ‘observed’ reflections. Crystals are orthorhombic, with space group P bca, a 13.684(6), b 11.602(4), c 11.171(4) Å, Z 8. The ring is a chair structure in which, contrary to an earlier proposal based on 1H n.m.r. studies, there is almost perfect staggering about the C(2)-C(3) bond.

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ER -

The Crystal and Molecular Structure of (±)-(‘E, ’)-N-Acetylpiperidine-2-carboxylic Acid

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