The crystal structure of mawbyite, PbFe2(AsO4)2(OH)2

null Kharisun; M. R. Taylor; D. J M Bevan; A. D. Rae; A. Pring

doi:10.1180/minmag.1997.061.408.07P

The crystal structure of mawbyite, PbFe₂(AsO₄)₂(OH)₂

Kharisun, M. R. Taylor, D. J M Bevan, A. D. Rae, A. Pring

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The crystal structure of mawbyite, PbFe₂(AsO₄)₂(OH)₂ has been refined. The mineral is monoclinic, C2/m with a = 9.066(4), b = 6.286(3) c = 7.564(3) Å, β = 114.857(5)°, Z = 2; the structure has been refined to a conventional R = 4.3% using 361 observed reflections [I> 3σ(I)]. The structure contains chains of edgesharing Fe(O,OH)₆, octahedra which are linked by AsO₄ tetrahedra and Pb atoms in distorted square antiprismatic co-ordination. The hydrogen bonding network in the structure has been modelled using bond valence calculations. Mawbyite is confirmed to be isostructural with tsumcorite and dimorphous with carminite and the relationship between these two structures is discussed.

Original language	English
Pages (from-to)	685-691
Number of pages	7
Journal	Mineralogical Magazine
Volume	61
Issue number	408
DOIs	https://doi.org/10.1180/minmag.1997.061.408.07P
Publication status	Published - 1 Oct 1997

Keywords

Arsenate
Broken Hill
Crystal structure
Mawbyite
New South Wales

Access to Document

10.1180/minmag.1997.061.408.07PLicence: In Copyright

Cite this

@article{b1cdff0ee22449e5b28f0e2dd8e50607,

title = "The crystal structure of mawbyite, PbFe2(AsO4)2(OH)2",

abstract = "The crystal structure of mawbyite, PbFe2(AsO4)2(OH)2 has been refined. The mineral is monoclinic, C2/m with a = 9.066(4), b = 6.286(3) c = 7.564(3) {\AA}, β = 114.857(5)°, Z = 2; the structure has been refined to a conventional R = 4.3% using 361 observed reflections [I> 3σ(I)]. The structure contains chains of edgesharing Fe(O,OH)6, octahedra which are linked by AsO4 tetrahedra and Pb atoms in distorted square antiprismatic co-ordination. The hydrogen bonding network in the structure has been modelled using bond valence calculations. Mawbyite is confirmed to be isostructural with tsumcorite and dimorphous with carminite and the relationship between these two structures is discussed.",

keywords = "Arsenate, Broken Hill, Crystal structure, Mawbyite, New South Wales",

author = "Kharisun and Taylor, {M. R.} and Bevan, {D. J M} and Rae, {A. D.} and A. Pring",

year = "1997",

month = oct,

day = "1",

doi = "10.1180/minmag.1997.061.408.07P",

language = "English",

volume = "61",

pages = "685--691",

journal = "Mineralogical Magazine",

issn = "0026-461X",

publisher = "Mineralogical Society",

number = "408",

}

TY - JOUR

T1 - The crystal structure of mawbyite, PbFe2(AsO4)2(OH)2

AU - Kharisun, null

AU - Taylor, M. R.

AU - Bevan, D. J M

AU - Rae, A. D.

AU - Pring, A.

PY - 1997/10/1

Y1 - 1997/10/1

N2 - The crystal structure of mawbyite, PbFe2(AsO4)2(OH)2 has been refined. The mineral is monoclinic, C2/m with a = 9.066(4), b = 6.286(3) c = 7.564(3) Å, β = 114.857(5)°, Z = 2; the structure has been refined to a conventional R = 4.3% using 361 observed reflections [I> 3σ(I)]. The structure contains chains of edgesharing Fe(O,OH)6, octahedra which are linked by AsO4 tetrahedra and Pb atoms in distorted square antiprismatic co-ordination. The hydrogen bonding network in the structure has been modelled using bond valence calculations. Mawbyite is confirmed to be isostructural with tsumcorite and dimorphous with carminite and the relationship between these two structures is discussed.

AB - The crystal structure of mawbyite, PbFe2(AsO4)2(OH)2 has been refined. The mineral is monoclinic, C2/m with a = 9.066(4), b = 6.286(3) c = 7.564(3) Å, β = 114.857(5)°, Z = 2; the structure has been refined to a conventional R = 4.3% using 361 observed reflections [I> 3σ(I)]. The structure contains chains of edgesharing Fe(O,OH)6, octahedra which are linked by AsO4 tetrahedra and Pb atoms in distorted square antiprismatic co-ordination. The hydrogen bonding network in the structure has been modelled using bond valence calculations. Mawbyite is confirmed to be isostructural with tsumcorite and dimorphous with carminite and the relationship between these two structures is discussed.

KW - Arsenate

KW - Broken Hill

KW - Crystal structure

KW - Mawbyite

KW - New South Wales

UR - http://www.scopus.com/inward/record.url?scp=0031417702&partnerID=8YFLogxK

U2 - 10.1180/minmag.1997.061.408.07P

DO - 10.1180/minmag.1997.061.408.07P

M3 - Article

AN - SCOPUS:0031417702

SN - 0026-461X

VL - 61

SP - 685

EP - 691

JO - Mineralogical Magazine

JF - Mineralogical Magazine

IS - 408

ER -

The crystal structure of mawbyite, PbFe₂(AsO₄)₂(OH)₂

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this