The effect of the activation process and metal oxide addition (CaO, MgO, SrO) on the catalytic and physicochemical properties of natural zeolite in transesterification reaction

Pawel Mierczynski; Lukasz Szkudlarek; Karolina Chalupka; Waldemar Maniukiewicz; Satriyo K. Wahono; Krasimir Vasilev; Malgorzata I. Szynkowska-Jozwik

doi:10.3390/ma14092415

The effect of the activation process and metal oxide addition (CaO, MgO, SrO) on the catalytic and physicochemical properties of natural zeolite in transesterification reaction

Pawel Mierczynski, Lukasz Szkudlarek, Karolina Chalupka, Waldemar Maniukiewicz, Satriyo K. Wahono, Krasimir Vasilev, Malgorzata I. Szynkowska-Jozwik

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Abstract

This work provides valuable information about unexplored catalytic systems tested in the transesterification reaction of vegetable oil with methanol. It was demonstrated that natural zeolite treatment leads to enhanced catalytic activity and yield of biodiesel production. The activation of the catalytic material in a mixture of 5% H₂-95% Ar resulted in an improvement of the values of the TG conversion and fatty acid methyl esters (FAME) yield. In addition, it was proven that the incorporation of CaO, MgO and SrO oxides onto the natural zeolite surface improves the TG conversion and FAME yield values in the transesterification reaction.

Original language	English
Article number	2415
Number of pages	16
Journal	Materials
Volume	14
Issue number	9
DOIs	https://doi.org/10.3390/ma14092415
Publication status	Published - 1 May 2021
Externally published	Yes

Keywords

Biodiesel production
FAME
Metal-oxide catalyst
Zeolite

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10.3390/ma14092415Licence: CC BY

Published versionFinal published version, 4.59 MBLicence: CC BY

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title = "The effect of the activation process and metal oxide addition (CaO, MgO, SrO) on the catalytic and physicochemical properties of natural zeolite in transesterification reaction",

abstract = "This work provides valuable information about unexplored catalytic systems tested in the transesterification reaction of vegetable oil with methanol. It was demonstrated that natural zeolite treatment leads to enhanced catalytic activity and yield of biodiesel production. The activation of the catalytic material in a mixture of 5% H2-95% Ar resulted in an improvement of the values of the TG conversion and fatty acid methyl esters (FAME) yield. In addition, it was proven that the incorporation of CaO, MgO and SrO oxides onto the natural zeolite surface improves the TG conversion and FAME yield values in the transesterification reaction.",

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T1 - The effect of the activation process and metal oxide addition (CaO, MgO, SrO) on the catalytic and physicochemical properties of natural zeolite in transesterification reaction

AU - Mierczynski, Pawel

AU - Szkudlarek, Lukasz

AU - Chalupka, Karolina

AU - Maniukiewicz, Waldemar

AU - Wahono, Satriyo K.

AU - Vasilev, Krasimir

AU - Szynkowska-Jozwik, Malgorzata I.

PY - 2021/5/1

Y1 - 2021/5/1

N2 - This work provides valuable information about unexplored catalytic systems tested in the transesterification reaction of vegetable oil with methanol. It was demonstrated that natural zeolite treatment leads to enhanced catalytic activity and yield of biodiesel production. The activation of the catalytic material in a mixture of 5% H2-95% Ar resulted in an improvement of the values of the TG conversion and fatty acid methyl esters (FAME) yield. In addition, it was proven that the incorporation of CaO, MgO and SrO oxides onto the natural zeolite surface improves the TG conversion and FAME yield values in the transesterification reaction.

AB - This work provides valuable information about unexplored catalytic systems tested in the transesterification reaction of vegetable oil with methanol. It was demonstrated that natural zeolite treatment leads to enhanced catalytic activity and yield of biodiesel production. The activation of the catalytic material in a mixture of 5% H2-95% Ar resulted in an improvement of the values of the TG conversion and fatty acid methyl esters (FAME) yield. In addition, it was proven that the incorporation of CaO, MgO and SrO oxides onto the natural zeolite surface improves the TG conversion and FAME yield values in the transesterification reaction.

KW - Biodiesel production

KW - FAME

KW - Metal-oxide catalyst

KW - Zeolite

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U2 - 10.3390/ma14092415

DO - 10.3390/ma14092415

M3 - Article

AN - SCOPUS:85107532515

VL - 14

JO - Materials

JF - Materials

SN - 1996-1944

IS - 9

M1 - 2415

ER -

The effect of the activation process and metal oxide addition (CaO, MgO, SrO) on the catalytic and physicochemical properties of natural zeolite in transesterification reaction

Abstract

Keywords

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