The first structural characterization of a five coordinate aluminum trichloride-bidentate tertiary amine adduct, trichloro(1,4-dimethylpiperazine) aluminum (III)

J. L. Atwood; C. Jones; C. L. Raston; K. D. Robinson

doi:10.1080/13583149612331338647

The first structural characterization of a five coordinate aluminum trichloride-bidentate tertiary amine adduct, trichloro(1,4-dimethylpiperazine) aluminum (III)

J. L. Atwood, C. Jones, C. L. Raston, K. D. Robinson

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Treatment of 1,4-dimethylpiperazine with AlCl₃ affords the title compound, the X-ray crystal structure of which shows it to be a chelate complex with a trigonal bipyramidal aluminum center having one axial and two equatorial chloride ligands.

Original language	English
Pages (from-to)	345-347
Number of pages	3
Journal	Main Group Chemistry
Volume	1
Issue number	3
DOIs	https://doi.org/10.1080/13583149612331338647
Publication status	Published - 1 Jan 1996
Externally published	Yes

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title = "The first structural characterization of a five coordinate aluminum trichloride-bidentate tertiary amine adduct, trichloro(1,4-dimethylpiperazine) aluminum (III)",

abstract = "Treatment of 1,4-dimethylpiperazine with AlCl3 affords the title compound, the X-ray crystal structure of which shows it to be a chelate complex with a trigonal bipyramidal aluminum center having one axial and two equatorial chloride ligands.",

author = "Atwood, {J. L.} and C. Jones and Raston, {C. L.} and Robinson, {K. D.}",

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AU - Atwood, J. L.

AU - Jones, C.

AU - Raston, C. L.

AU - Robinson, K. D.

PY - 1996/1/1

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N2 - Treatment of 1,4-dimethylpiperazine with AlCl3 affords the title compound, the X-ray crystal structure of which shows it to be a chelate complex with a trigonal bipyramidal aluminum center having one axial and two equatorial chloride ligands.

AB - Treatment of 1,4-dimethylpiperazine with AlCl3 affords the title compound, the X-ray crystal structure of which shows it to be a chelate complex with a trigonal bipyramidal aluminum center having one axial and two equatorial chloride ligands.

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DO - 10.1080/13583149612331338647

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ER -

The first structural characterization of a five coordinate aluminum trichloride-bidentate tertiary amine adduct, trichloro(1,4-dimethylpiperazine) aluminum (III)

Abstract

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