The template-directed synthesis of porphyrin-stoppered [2]rotaxanes

Peter R. Ashton; Martin R. Johnston; J. Fraser Stoddart; Malcolm S. Tolley; John W. Wheeler

doi:10.1039/C39920001128

The template-directed synthesis of porphyrin-stoppered [2]rotaxanes

Peter R. Ashton, Martin R. Johnston, J. Fraser Stoddart, Malcolm S. Tolley, John W. Wheeler

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

Two [2]rotaxanes, composed of (i) a polyether chain intercepted by (a) one centrally-located and (b) two symmetrically-located π-electron-rich hydroquinol rings and terminated by free-base and metallated (Zn) tetraaryl-porphyrin groups respectively and (ii) a tetracationic cyclophane constructed of two π-electron-deficient bipyridinium units linked by paraphenylenedimethyl residues, have been self-assembled by a clipping procedure.

Original language	English
Pages (from-to)	1128-1131
Number of pages	4
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39920001128
Publication status	Published - 1992
Externally published	Yes

Access to Document

10.1039/C39920001128Licence: In Copyright

Cite this

@article{c09b29fb3db54edeb632f1598cd5d1ff,

title = "The template-directed synthesis of porphyrin-stoppered [2]rotaxanes",

abstract = "Two [2]rotaxanes, composed of (i) a polyether chain intercepted by (a) one centrally-located and (b) two symmetrically-located π-electron-rich hydroquinol rings and terminated by free-base and metallated (Zn) tetraaryl-porphyrin groups respectively and (ii) a tetracationic cyclophane constructed of two π-electron-deficient bipyridinium units linked by paraphenylenedimethyl residues, have been self-assembled by a clipping procedure.",

author = "Ashton, {Peter R.} and Johnston, {Martin R.} and Stoddart, {J. Fraser} and Tolley, {Malcolm S.} and Wheeler, {John W.}",

year = "1992",

doi = "10.1039/C39920001128",

language = "English",

pages = "1128--1131",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "16",

}

TY - JOUR

T1 - The template-directed synthesis of porphyrin-stoppered [2]rotaxanes

AU - Ashton, Peter R.

AU - Johnston, Martin R.

AU - Stoddart, J. Fraser

AU - Tolley, Malcolm S.

AU - Wheeler, John W.

PY - 1992

Y1 - 1992

N2 - Two [2]rotaxanes, composed of (i) a polyether chain intercepted by (a) one centrally-located and (b) two symmetrically-located π-electron-rich hydroquinol rings and terminated by free-base and metallated (Zn) tetraaryl-porphyrin groups respectively and (ii) a tetracationic cyclophane constructed of two π-electron-deficient bipyridinium units linked by paraphenylenedimethyl residues, have been self-assembled by a clipping procedure.

AB - Two [2]rotaxanes, composed of (i) a polyether chain intercepted by (a) one centrally-located and (b) two symmetrically-located π-electron-rich hydroquinol rings and terminated by free-base and metallated (Zn) tetraaryl-porphyrin groups respectively and (ii) a tetracationic cyclophane constructed of two π-electron-deficient bipyridinium units linked by paraphenylenedimethyl residues, have been self-assembled by a clipping procedure.

UR - http://www.scopus.com/inward/record.url?scp=37049082998&partnerID=8YFLogxK

U2 - 10.1039/C39920001128

DO - 10.1039/C39920001128

M3 - Article

AN - SCOPUS:37049082998

SN - 0022-4936

SP - 1128

EP - 1131

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

The template-directed synthesis of porphyrin-stoppered [2]rotaxanes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this