The trans-[py2AlCl4]- ('py' = pyridine) anion, structurally characterized in two pyridinium salts

Peter C. Junk; Colin L. Raston; Brian W. Skelton; Allan H. White

doi:10.1071/CH03206

The trans-[py₂AlCl₄]^- ('py' = pyridine) anion, structurally characterized in two pyridinium salts

Peter C. Junk, Colin L. Raston, Brian W. Skelton, Allan H. White

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Salts of the trans-[py₂AlCl₄]^- anion have been structurally characterized by 'low'-temperature single crystal structure determinations of the adducts 2AlCl₃ · 2HC1 · 4py {=(pyH)₂[(py)₂AlCl₄](AlCl₄)}, and 2AlCl₃ · 3HC1 · 7py {=(pyH)₃[(py) ₂AlCl₄]₂Cl}, extending the structurally characterized members of the array [(py)_nAlCl_(6-n)] ^(n-3)± with 'octahedral' six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.

Original language	English
Pages (from-to)	503-506
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	57
Issue number	5
DOIs	https://doi.org/10.1071/CH03206
Publication status	Published - 7 May 2004
Externally published	Yes

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title = "The trans-[py2AlCl4]- ('py' = pyridine) anion, structurally characterized in two pyridinium salts",

abstract = "Salts of the trans-[py2AlCl4]- anion have been structurally characterized by 'low'-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HC1 · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HC1 · 7py {=(pyH)3[(py) 2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6-n)] (n-3)± with 'octahedral' six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.",

author = "Junk, {Peter C.} and Raston, {Colin L.} and Skelton, {Brian W.} and White, {Allan H.}",

year = "2004",

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doi = "10.1071/CH03206",

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journal = "Australian Journal of Chemistry",

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T1 - The trans-[py2AlCl4]- ('py' = pyridine) anion, structurally characterized in two pyridinium salts

AU - Junk, Peter C.

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 2004/5/7

Y1 - 2004/5/7

N2 - Salts of the trans-[py2AlCl4]- anion have been structurally characterized by 'low'-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HC1 · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HC1 · 7py {=(pyH)3[(py) 2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6-n)] (n-3)± with 'octahedral' six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.

AB - Salts of the trans-[py2AlCl4]- anion have been structurally characterized by 'low'-temperature single crystal structure determinations of the adducts 2AlCl3 · 2HC1 · 4py {=(pyH)2[(py)2AlCl4](AlCl4)}, and 2AlCl3 · 3HC1 · 7py {=(pyH)3[(py) 2AlCl4]2Cl}, extending the structurally characterized members of the array [(py)nAlCl(6-n)] (n-3)± with 'octahedral' six-coordinate metal atom geometries, the members for n = 3 (mer) and 4 (trans) having been previously characterized.

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DO - 10.1071/CH03206

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SN - 0004-9425

VL - 57

SP - 503

EP - 506

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 5

ER -

The trans-[py₂AlCl₄]^- ('py' = pyridine) anion, structurally characterized in two pyridinium salts

Abstract

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