Thermal unimolecular reactions in the fall-off regime: A master equation analysis

Warren D. Lawrance; Alan E.W. Knight; Robert G. Gilbert; Keith D. King

doi:10.1016/0009-2614(80)80616-6

Thermal unimolecular reactions in the fall-off regime: A master equation analysis

Warren D. Lawrance, Alan E.W. Knight, Robert G. Gilbert, Keith D. King

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5 Citations (Scopus)

Abstract

A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF₆ decomposition are obtained in an illustrative calculation.

Original language	English
Pages (from-to)	113-116
Number of pages	4
Journal	Chemical Physics Letters
Volume	76
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(80)80616-6
Publication status	Published - 15 Nov 1980
Externally published	Yes

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title = "Thermal unimolecular reactions in the fall-off regime: A master equation analysis",

abstract = "A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF6 decomposition are obtained in an illustrative calculation.",

author = "Lawrance, {Warren D.} and Knight, {Alan E.W.} and Gilbert, {Robert G.} and King, {Keith D.}",

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AU - Lawrance, Warren D.

AU - Knight, Alan E.W.

AU - Gilbert, Robert G.

AU - King, Keith D.

PY - 1980/11/15

Y1 - 1980/11/15

N2 - A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF6 decomposition are obtained in an illustrative calculation.

AB - A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF6 decomposition are obtained in an illustrative calculation.

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DO - 10.1016/0009-2614(80)80616-6

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VL - 76

SP - 113

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

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Thermal unimolecular reactions in the fall-off regime: A master equation analysis

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