Thermal unimolecular reactions in the fall-off regime: A master equation analysis

Warren D. Lawrance; Alan E.W. Knight; Robert G. Gilbert; Keith D. King

doi:10.1016/0009-2614(80)80616-6

Thermal unimolecular reactions in the fall-off regime: A master equation analysis

Warren D. Lawrance
, Alan E.W. Knight
, Robert G. Gilbert
, Keith D. King

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF₆ decomposition are obtained in an illustrative calculation.

Original language	English
Pages (from-to)	113-116
Number of pages	4
Journal	Chemical Physics Letters
Volume	76
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(80)80616-6
Publication status	Published - 15 Nov 1980
Externally published	Yes

Access to Document

10.1016/0009-2614(80)80616-6Licence: In Copyright

Cite this

@article{1c634f3539fe404d98ce6d4b43ec7059,

title = "Thermal unimolecular reactions in the fall-off regime: A master equation analysis",

abstract = "A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF6 decomposition are obtained in an illustrative calculation.",

author = "Lawrance, \{Warren D.\} and Knight, \{Alan E.W.\} and Gilbert, \{Robert G.\} and King, \{Keith D.\}",

year = "1980",

month = nov,

day = "15",

doi = "10.1016/0009-2614(80)80616-6",

language = "English",

volume = "76",

pages = "113--116",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Thermal unimolecular reactions in the fall-off regime

T2 - A master equation analysis

AU - Lawrance, Warren D.

AU - Knight, Alan E.W.

AU - Gilbert, Robert G.

AU - King, Keith D.

PY - 1980/11/15

Y1 - 1980/11/15

N2 - A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF6 decomposition are obtained in an illustrative calculation.

AB - A technique for combining RRKM theory with a master equation approach is applied to the analysis of thermal unimolecular data in the fall-off regime. Microscopic rates for SF6 decomposition are obtained in an illustrative calculation.

UR - https://www.scopus.com/pages/publications/57349127373

U2 - 10.1016/0009-2614(80)80616-6

DO - 10.1016/0009-2614(80)80616-6

M3 - Article

AN - SCOPUS:57349127373

SN - 0009-2614

VL - 76

SP - 113

EP - 116

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

Thermal unimolecular reactions in the fall-off regime: A master equation analysis

Abstract

Access to Document

Other files and links

Fingerprint

Cite this