Topological control in paddlewheel metal-organic cages via ligand length variation

Steven Tsoukatos; Ashakiran Maibam; Ravichandar Babarao; Witold M. Bloch

doi:10.1039/d4cc03769c

Topological control in paddlewheel metal-organic cages via ligand length variation

Steven Tsoukatos, Ashakiran Maibam, Ravichandar Babarao, Witold M. Bloch

Research output: Contribution to journal › Article › peer-review

Abstract

Varying the length of phenanthrene-derived ligands switches the selective assembly of M^II_nL_n metal-organic cages (MOCs, n = 6 or 8) between tetrahedral, square, or triangular architectures. The limit of this approach is explored for both Cu₂ and Rh₂ paddlewheel MOCs, and supported by solution, solid-state and computational analysis.

Original language	English
Pages (from-to)	13183-13186
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	90
DOIs	https://doi.org/10.1039/d4cc03769c
Publication status	Published - 21 Nov 2024

Keywords

phenanthrene-derived ligands
ligand
metal–organic cages
Cu2
Rh2
paddlewheel MOCs

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abstract = "Varying the length of phenanthrene-derived ligands switches the selective assembly of MIInLn metal-organic cages (MOCs, n = 6 or 8) between tetrahedral, square, or triangular architectures. The limit of this approach is explored for both Cu2 and Rh2 paddlewheel MOCs, and supported by solution, solid-state and computational analysis.",

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AU - Maibam, Ashakiran

AU - Babarao, Ravichandar

AU - Bloch, Witold M.

PY - 2024/11/21

Y1 - 2024/11/21

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KW - ligand

KW - metal–organic cages

KW - Cu2

KW - Rh2

KW - paddlewheel MOCs

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Topological control in paddlewheel metal-organic cages via ligand length variation

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