Tuning the Energy Level Offset between Donor and Acceptor with Ferroelectric Dipole Layers for Increased Efficiency in Bilayer Organic Photovoltaic Cells

Bin Yang; Yongbo Yuan; Pankaj Sharma; Shashi Poddar; Rafal Korlacki; Stephen Ducharme; Alexei Gruverman; Ravi Saraf; Jinsong Huang

doi:10.1002/adma.201104509

Tuning the Energy Level Offset between Donor and Acceptor with Ferroelectric Dipole Layers for Increased Efficiency in Bilayer Organic Photovoltaic Cells

Bin Yang
, Yongbo Yuan
, Pankaj Sharma
, Shashi Poddar
, Rafal Korlacki
, Stephen Ducharme
, Alexei Gruverman
, Ravi Saraf
, Jinsong Huang

Research output: Contribution to journal › Article › peer-review

134 Citations (Scopus)

Abstract

Ultrathin ferroelectric polyvinylidene fluoride (70%)-tetrafluoroethylene (30%) copolymer film is inserted between the poly3(hexylthiophene) (P3HT) donor and [6,6]-phenyl-C61-butyric acid methylester (PCBM) acceptor layers as the dipole layer to tune the relative energy levels, which can potentially maximize the open circuit voltage of bilayer organic solar cells. In this work, the power conversion efficiency of P3HT/PCBM bilayer solar cells is demonstrated to be doubled with the inserted dipoles.

Original language	English
Pages (from-to)	1455-1460
Number of pages	6
Journal	Advanced Materials
Volume	24
Issue number	11
DOIs	https://doi.org/10.1002/adma.201104509
Publication status	Published - 15 Mar 2012
Externally published	Yes

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SDG 7 Affordable and Clean Energy

Keywords

dipole
ferroelectrics
open circuit voltage
organic photovoltaics

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10.1002/adma.201104509Licence: In Copyright

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title = "Tuning the Energy Level Offset between Donor and Acceptor with Ferroelectric Dipole Layers for Increased Efficiency in Bilayer Organic Photovoltaic Cells",

abstract = "Ultrathin ferroelectric polyvinylidene fluoride (70\%)-tetrafluoroethylene (30\%) copolymer film is inserted between the poly3(hexylthiophene) (P3HT) donor and [6,6]-phenyl-C61-butyric acid methylester (PCBM) acceptor layers as the dipole layer to tune the relative energy levels, which can potentially maximize the open circuit voltage of bilayer organic solar cells. In this work, the power conversion efficiency of P3HT/PCBM bilayer solar cells is demonstrated to be doubled with the inserted dipoles.",

keywords = "dipole, ferroelectrics, open circuit voltage, organic photovoltaics",

author = "Bin Yang and Yongbo Yuan and Pankaj Sharma and Shashi Poddar and Rafal Korlacki and Stephen Ducharme and Alexei Gruverman and Ravi Saraf and Jinsong Huang",

year = "2012",

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doi = "10.1002/adma.201104509",

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T1 - Tuning the Energy Level Offset between Donor and Acceptor with Ferroelectric Dipole Layers for Increased Efficiency in Bilayer Organic Photovoltaic Cells

AU - Yang, Bin

AU - Yuan, Yongbo

AU - Sharma, Pankaj

AU - Poddar, Shashi

AU - Korlacki, Rafal

AU - Ducharme, Stephen

AU - Gruverman, Alexei

AU - Saraf, Ravi

AU - Huang, Jinsong

PY - 2012/3/15

Y1 - 2012/3/15

N2 - Ultrathin ferroelectric polyvinylidene fluoride (70%)-tetrafluoroethylene (30%) copolymer film is inserted between the poly3(hexylthiophene) (P3HT) donor and [6,6]-phenyl-C61-butyric acid methylester (PCBM) acceptor layers as the dipole layer to tune the relative energy levels, which can potentially maximize the open circuit voltage of bilayer organic solar cells. In this work, the power conversion efficiency of P3HT/PCBM bilayer solar cells is demonstrated to be doubled with the inserted dipoles.

AB - Ultrathin ferroelectric polyvinylidene fluoride (70%)-tetrafluoroethylene (30%) copolymer film is inserted between the poly3(hexylthiophene) (P3HT) donor and [6,6]-phenyl-C61-butyric acid methylester (PCBM) acceptor layers as the dipole layer to tune the relative energy levels, which can potentially maximize the open circuit voltage of bilayer organic solar cells. In this work, the power conversion efficiency of P3HT/PCBM bilayer solar cells is demonstrated to be doubled with the inserted dipoles.

KW - dipole

KW - ferroelectrics

KW - open circuit voltage

KW - organic photovoltaics

UR - https://www.scopus.com/pages/publications/84863348058

U2 - 10.1002/adma.201104509

DO - 10.1002/adma.201104509

M3 - Article

C2 - 22328442

AN - SCOPUS:84863348058

SN - 0935-9648

VL - 24

SP - 1455

EP - 1460

JO - Advanced Materials

JF - Advanced Materials

IS - 11

ER -

Tuning the Energy Level Offset between Donor and Acceptor with Ferroelectric Dipole Layers for Increased Efficiency in Bilayer Organic Photovoltaic Cells

Abstract

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Keywords

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