Unlocking the elusive binding cavity in p-sulfonatocalix[8]arene

Christopher B. Smith; Leonard J. Barbour; Mohamed Makha; Colin L. Raston; Alexandre N. Sobolev

doi:10.1039/b604513h

Unlocking the elusive binding cavity in p-sulfonatocalix[8]arene

Christopher B. Smith, Leonard J. Barbour, Mohamed Makha, Colin L. Raston, Alexandre N. Sobolev

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

For the first time the utility of p-sulfonatocalix[8]arene to form a chalice-like cavity for the solid state inclusion of a classical coordination complex [Co(phen)₃]³⁺ has been demonstrated. In the presence of Yb³⁺ ions, a new crystalline material is formed which possesses large diameter, negatively charged channels which propagate through the material in three dimensions.

Original language	English
Pages (from-to)	991-996
Number of pages	6
Journal	New Journal of Chemistry
Volume	30
Issue number	7
DOIs	https://doi.org/10.1039/b604513h
Publication status	Published - 11 Jul 2006
Externally published	Yes

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abstract = "For the first time the utility of p-sulfonatocalix[8]arene to form a chalice-like cavity for the solid state inclusion of a classical coordination complex [Co(phen)3]3+ has been demonstrated. In the presence of Yb3+ ions, a new crystalline material is formed which possesses large diameter, negatively charged channels which propagate through the material in three dimensions.",

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AU - Raston, Colin L.

AU - Sobolev, Alexandre N.

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AB - For the first time the utility of p-sulfonatocalix[8]arene to form a chalice-like cavity for the solid state inclusion of a classical coordination complex [Co(phen)3]3+ has been demonstrated. In the presence of Yb3+ ions, a new crystalline material is formed which possesses large diameter, negatively charged channels which propagate through the material in three dimensions.

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Unlocking the elusive binding cavity in p-sulfonatocalix[8]arene

Abstract

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