Unravelling the structure of the C60 and p-But -calix (8) arene complex

Xianjue Chen; Ramiz Boulos; Ashley Slattery; Jerry Atwood; Colin Raston

doi:10.1039/c5cc03941j

Unravelling the structure of the C60 and p-But -calix (8) arene complex

Xianjue Chen, Ramiz Boulos, Ashley Slattery, Jerry Atwood, Colin Raston

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The structure of the C₆₀ and p-Bu^t-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C₇₀ in place of the smaller fullerene.

Original language	English
Pages (from-to)	11413-11416
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	57
DOIs	https://doi.org/10.1039/c5cc03941j
Publication status	Published - 21 Jul 2015

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abstract = "The structure of the C60 and p-But-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C70 in place of the smaller fullerene.",

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AU - Chen, Xianjue

AU - Boulos, Ramiz

AU - Slattery, Ashley

AU - Atwood, Jerry

AU - Raston, Colin

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N2 - The structure of the C60 and p-But-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C70 in place of the smaller fullerene.

AB - The structure of the C60 and p-But-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C70 in place of the smaller fullerene.

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DO - 10.1039/c5cc03941j

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 57

ER -

Unravelling the structure of the C60 and p-But -calix (8) arene complex

Abstract

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