Unravelling the structure of the C60 and p-But -calix (8) arene complex

Xianjue Chen; Ramiz Boulos; Ashley Slattery; Jerry Atwood; Colin Raston

doi:10.1039/c5cc03941j

Unravelling the structure of the C60 and p-But -calix (8) arene complex

Xianjue Chen, Ramiz Boulos, Ashley Slattery, Jerry Atwood, Colin Raston

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The structure of the C₆₀ and p-Bu^t-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C₇₀ in place of the smaller fullerene.

Original language	English
Pages (from-to)	11413-11416
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	57
DOIs	https://doi.org/10.1039/c5cc03941j
Publication status	Published - 21 Jul 2015

Access to Document

10.1039/c5cc03941j

Cite this

@article{dad654b2c39545a0a935bb48d1d58c90,

title = "Unravelling the structure of the C60 and p-But -calix (8) arene complex",

abstract = "The structure of the C60 and p-But-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C70 in place of the smaller fullerene.",

author = "Xianjue Chen and Ramiz Boulos and Ashley Slattery and Jerry Atwood and Colin Raston",

year = "2015",

month = jul,

day = "21",

doi = "10.1039/c5cc03941j",

language = "English",

volume = "51",

pages = "11413--11416",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "57",

}

TY - JOUR

T1 - Unravelling the structure of the C60 and p-But -calix (8) arene complex

AU - Chen, Xianjue

AU - Boulos, Ramiz

AU - Slattery, Ashley

AU - Atwood, Jerry

AU - Raston, Colin

PY - 2015/7/21

Y1 - 2015/7/21

N2 - The structure of the C60 and p-But-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C70 in place of the smaller fullerene.

AB - The structure of the C60 and p-But-calix[8]arene complex has been reinvestigated, showing an unprecedented continuous layered tetragonal array of fullerenes encapsulated by calixarenes. Electron diffraction data revealed the tetragonal symmetry, with a stepped structure observed by AFM and SEM, and the thickness of the basal plane was measured by XRD, as 2 nm. The molecular simulated arrangement of fullerenes accounts for the ability to take up to ca. 11% of fullerenes C70 in place of the smaller fullerene.

UR - http://www.scopus.com/inward/record.url?scp=84953924052&partnerID=8YFLogxK

U2 - 10.1039/c5cc03941j

DO - 10.1039/c5cc03941j

M3 - Article

SN - 1359-7345

VL - 51

SP - 11413

EP - 11416

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Unravelling the structure of the C60 and p-But -calix (8) arene complex

Abstract

Access to Document

Other files and links

Fingerprint

Cite this