Vortex Fluidic Ethenolysis, Integrating a Rapid Quench of Ruthenium Olefin Metathesis Catalysts

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Abstract

Ruthenium-catalysed ethenolysis occurs in a vortex fluidic device (VFD)-a scalable, thin-film microfluidic continuous flow process. This process takes advantage of the efficient mass transfer of gaseous reagents into the dynamic thin film of liquid. Also reported is the rapid quenching of the ruthenium-based olefin metathesis catalyst by the addition of a saturated solution of N-acetyl-l-cysteine in MeCN, as a convenient alternative to previously reported quenching methods.

Original languageEnglish
Pages (from-to)1138-1143
Number of pages6
JournalAustralian Journal of Chemistry
Volume73
Issue number12
Early online date26 Jun 2020
DOIs
Publication statusPublished - Dec 2020

Keywords

  • Vortex Fluidic
  • Ethenolysis
  • Ruthenium
  • Olefin
  • Metathesis Catalysts

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