Zinc dimerization of p-tert-butylcalix[4]arene

Jerry L. Atwood; Peter C. Junk; Stacey M. Lawrence; Colin L. Raston

doi:10.1080/10610279608054990

Zinc dimerization of p-tert-butylcalix[4]arene

Jerry L. Atwood, Peter C. Junk, Stacey M. Lawrence, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt₂ results in complete metallation of the calixarene, or with two equivalents of ZnEt₂ selective dimetallation occurs yielding the bis(calix[4]arene) species [{1-H₂)Zn}₂], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) Å) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.

Original language	English
Pages (from-to)	15-17
Number of pages	3
Journal	Supramolecular Chemistry
Volume	7
Issue number	1
DOIs	https://doi.org/10.1080/10610279608054990
Publication status	Published - 1 Jan 1996
Externally published	Yes

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title = "Zinc dimerization of p-tert-butylcalix[4]arene",

abstract = "Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt2 results in complete metallation of the calixarene, or with two equivalents of ZnEt2 selective dimetallation occurs yielding the bis(calix[4]arene) species [{1-H2)Zn}2], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) {\AA}) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.",

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AU - Junk, Peter C.

AU - Lawrence, Stacey M.

AU - Raston, Colin L.

PY - 1996/1/1

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N2 - Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt2 results in complete metallation of the calixarene, or with two equivalents of ZnEt2 selective dimetallation occurs yielding the bis(calix[4]arene) species [{1-H2)Zn}2], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) Å) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.

AB - Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt2 results in complete metallation of the calixarene, or with two equivalents of ZnEt2 selective dimetallation occurs yielding the bis(calix[4]arene) species [{1-H2)Zn}2], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) Å) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.

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Zinc dimerization of p-tert-butylcalix[4]arene

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