Zinc dimerization of p-tert-butylcalix[4]arene

Jerry L. Atwood; Peter C. Junk; Stacey M. Lawrence; Colin L. Raston

doi:10.1080/10610279608054990

Zinc dimerization of p-tert-butylcalix[4]arene

Jerry L. Atwood
, Peter C. Junk
, Stacey M. Lawrence
, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt₂ results in complete metallation of the calixarene, or with two equivalents of ZnEt₂ selective dimetallation occurs yielding the bis(calix[4]arene) species [{1-H₂)Zn}₂], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) Å) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.

Original language	English
Pages (from-to)	15-17
Number of pages	3
Journal	Supramolecular Chemistry
Volume	7
Issue number	1
DOIs	https://doi.org/10.1080/10610279608054990
Publication status	Published - 1 Jan 1996
Externally published	Yes

Access to Document

10.1080/10610279608054990Licence: In Copyright

Cite this

@article{558cba34a6c640bcb27f260235fc7e76,

title = "Zinc dimerization of p-tert-butylcalix[4]arene",

abstract = "Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt2 results in complete metallation of the calixarene, or with two equivalents of ZnEt2 selective dimetallation occurs yielding the bis(calix[4]arene) species [\{1-H2)Zn\}2], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) {\AA}) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.",

author = "Atwood, \{Jerry L.\} and Junk, \{Peter C.\} and Lawrence, \{Stacey M.\} and Raston, \{Colin L.\}",

year = "1996",

month = jan,

day = "1",

doi = "10.1080/10610279608054990",

language = "English",

volume = "7",

pages = "15--17",

journal = "Supramolecular Chemistry",

issn = "1061-0278",

publisher = "Taylor \& Francis",

number = "1",

}

TY - JOUR

T1 - Zinc dimerization of p-tert-butylcalix[4]arene

AU - Atwood, Jerry L.

AU - Junk, Peter C.

AU - Lawrence, Stacey M.

AU - Raston, Colin L.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt2 results in complete metallation of the calixarene, or with two equivalents of ZnEt2 selective dimetallation occurs yielding the bis(calix[4]arene) species [{1-H2)Zn}2], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) Å) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.

AB - Reaction of p-tert-butylcalix[4]arene, 1, with excess ZnEt2 results in complete metallation of the calixarene, or with two equivalents of ZnEt2 selective dimetallation occurs yielding the bis(calix[4]arene) species [{1-H2)Zn}2], 2; distorted four coordinate O-bound zinc centers (Zn-O = 1.896(7) - 1.978(8) Å) fuse the slightly flattened cone conformation calixarene units with methylene chloride included in the divergent cavities.

UR - https://www.scopus.com/pages/publications/0013101616

U2 - 10.1080/10610279608054990

DO - 10.1080/10610279608054990

M3 - Article

AN - SCOPUS:0013101616

SN - 1061-0278

VL - 7

SP - 15

EP - 17

JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

IS - 1

ER -

Zinc dimerization of p-tert-butylcalix[4]arene

Abstract

Access to Document

Other files and links

Fingerprint

Cite this